Chemically-engineered multipurpose spin selection in a double-level molecular device with spinterface

Curvature-enhanced Spin-orbit Coupling and Spinterface Effect in Fullerene-based Spin Valves

We investigated curvature-enhanced spin-orbit coupling (SOC) and spinterface effect in carbon-based organic spin valves (OSVs) using buckyball C60 and C70 molecules. Since the naturally abundant (12)C has spinless nuclear, the materials have negligible hyperfine interaction (HFI) and the same intrinsic SOC, but different curvature SOC due to their distinct curvatures. We fitted the thickness de...

Chemically doped double-walled carbon nanotubes: cylindrical molecular capacitors.

A double-walled carbon nanotube is used to study the radial charge distribution on the positive inner electrode of a cylindrical molecular capacitor. The outer electrode is a shell of bromine anions. Resonant Raman scattering from phonons on each carbon shell reveals the radial charge distribution. A self-consistent tight-binding model confirms the observed molecular Faraday cage effect, i.e., ...

Novel Optical Device Materials – Molecular-Level Hybridization

Chemically engineered persistent luminescence nanoprobes for bioimaging

Imaging nanoprobes are a group of nanosized agents developed for providing improved contrast for bioimaging. Among various imaging probes, optical sensors capable of following biological events or progresses at the cellular and molecular levels are actually actively developed for early detection, accurate diagnosis, and monitoring of the treatment of diseases. The optical activities of nanoprob...

Chemically Induced Dynamic Spin Polarization

The Pedersen-Freed theory for chemically induced dynamic spin polarization CIDN(E)P is generalized to include the effects of anisotropic reactivities and anisotropic exchange interactions on the radical-pair mechanism. Detailed results are given for the simple case in which only one radical exhibits anisotropy that is approximated by a cosine distribution, and the rotational and translational m...